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Chelsea matches where Diego Simeone was opposition manager/coach
| Date | Venue | Opponent | Score | Comp |
| 31/08/2012 | Stade Louis II Monaco | Atletico Madrid | 1-4 | UEFA Super Cup |
| 22/04/2014 | Vicente Calderon | Atletico Madrid | 0-0 | UEFA Champions League |
| 30/04/2014 | Stamford Bridge | Atletico Madrid | 1-3 | UEFA Champions League |
| 27/09/2017 | Estadio Metropolitano | Atletico Madrid | 2-1 | UEFA Champions League |
| 05/12/2017 | Stamford Bridge | Atletico Madrid | 1-1 | UEFA Champions League |
| 23/02/2021 | Arena Nationala, Bucharest | Atletico Madrid | 1-0 | UEFA Champions League |
| 17/03/2021 | Stamford Bridge | Atletico Madrid | 2-0 | UEFA Champions League |